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Graduate School of Engineering, Department of Applied Chemistry & Biotechnology Japanese

representative Publications (2004-Present)


Shinji Sugihara,* "From controlled radical polymerization of vinyl ether to polymerization-induced self-assembly", Polym. J. (2022)  

Hideyuki Uematsu, Naoki Higashitani, Ayaka Yamaguchi, Akinori Fukuishima, Takayuki Asano, Seitaro Mitsudo, Shinji Sugihara, Masachika Yamane, Toshihira Irisawa,Yukihiro Ozaki, ShuichiTanoue, "Effects of polycarbonate crystals, π-π interactions, and chemical bonds at an interface on the interfacial adhesion between polycarbonate and reinforcing fibers", Surf. Interfaces, 34, 102300 (2022)  

Atsushi Takashima, Yasushi Maeda, Shinji Sugihara,* "Morphology Control via RAFT Emulsion Polymerization-Induced Self-Assembly: Systematic Investigation of Core-Forming Blocks", ACS Omega, 7, 26894-26904 (2022)  

Narumi Asano, Shinji Sugihara, Shin-ichiro Suye, and Satoshi Fujita, Electrospun Porous Nanofibers with Imprinted Patterns Induced by Phase Separation of Immiscible Polymer Blends", ACS Omega, 7, 19997-20005 (2022)  
Hideyuki Uematsu, Kotaro Mune, Shunya Nishimura, Koutarou Koizumi, Ayaka Yamaguchi, Shinji Sugihara, Masachika Yamane, Kazumasa Kawabe, Yukihiro Ozaki, Shuichi Tanoue, "Fracture properties of quasi-isotropic carbon-fiber-reinforced polyamide 6 laminates with different crystal structure of polyamide 6 due to surface profiles of carbon fibers", Compos. Part A Appl. Sci. Manuf., 154, 106752 (2022)  
Hideyuki Uematsu,Takahiro Kawasaki, Koutaro Koizumi, Akane Yamaguchi, Shinji Sugihara, Masachika Yamane, Kazumasa Kawabe, Yukihiro Ozaki, Shuichi Tanoue, "Relationship between crystalline structure of polyamide 6 within carbon fibers and their mechanical propaerties studied using Micro-Raman spectroscopy", Polymer, 223, 123711 (2021)  

Shinji Sugihara, Ryuya Kawakami, Satoshi Irie, Yasushi Maeda, "Poly[di(ethylene glycol) vinyl ether]-stabilized poly(vinyl acetate) nanoparticles with various morphologies via RAFT aqueous emulsion polymerization of vinyl acetate", Polym. J., 53, 309-321 (2021)  

Satoshi Fujita, Saeri Hara, Akari Hosono, Shinji Sugihara, Hideyuki Uematsu, Shin-ichiro Suye, "Hyaluronic Acid Hydrogel Crosslinked with Complementary DNAs", Adv. Polym. Technol.,2020, 1470819 (2020)

Shinji Sugihara,* Ayano Yoshida, Taka-aki Kono, Tsuyoshi Takayama, Yasushi Maeda, "Controlled Radical Homopolymerization of Representative Cationically Polymerizable Vinyl Ethers", J. Am. Chem. Soc.,141, 13954-13961 (2019)

Shinji Sugihara,* Molecular Technology, Volume 4: Synthesis Innovation(H. Yamamoto, T.Kato ed.) Chapter 1. "Polymerization-Induced Self-assembly of Block Copolymer Nano-objects via Green RAFT Polymerization")
     
Shinji Sugihara,* Masahiro Sudo, Yasushi Maeda, "Synthesis and Nano-object Assembly of Biomimetic Block Copolymers for Catalytic Silver Nanoparticles", Langmuir 35, 1346-1356 (2019)     

Shinji Sugihara,* Yoshihiro Sakamoto, Masakazu Nakayama, Keigo Michishita, Yasushi Maeda,"Transformation from xanthate-type cationogen mediated metal-free RAFT cationic polymerization with “HCl·Et2O” into RAFT radical polymerization to form poly(alkyl vinyl ether)-b-polyvinyl alcohol amphiphiles", Polymer 154, 153-163 (2018)

Shinji Sugihara,* Masahiro Sudo, Kazumasa Hirogaki, Satoshi Irie, Yasushi Maeda, "Synthesis of Various Poly(2-hydroxyethyl vinyl ethe)-Stabilized Latex Particles via Surfactant-Free Emulsion Polymerization in Water", Macromolecules 51, 1260-1271 (2018)

Shinji Sugihara,* Ayano Yoshiada, Satoshi Fujita, Yasushi Maeda, "Design of Hydroxy- Functionalized Thermoresponsive Copolymers: Improved Direct Radical Polymerization of Hydroxy-Functional Vinyl Ethers", Macromolecules 50, 8346-8356 (2017)

Mugen Yamawaki, Akari Ukai, Yuki Kamiya, Shinji Sugihara,* Miku Sakai, Yasuharu Yoshimi,* "Metal-Free Photoinduced Decarboxylative Radical Polymerization Using Carboxylic Acids as Benign Radical Initiators: Introduction of Complex Molecules into Polymer Chain Ends", ACS Macro Letters, 6, 381-385(2017)

Shinji Sugihara,* Seiya Okubo, Yasushi Maeda, "Metal-free RAFT cationic polymerization of p-methoxystyrene with HCl・Et2O using a xanthate-type RAFT cationogen", Polymer Chemistry 7, 6854-6863 (2016)

Shinji Sugihara,* Yuki Kawamoto, Yasushi Maeda, "Direct Radical Polymerization of Vinyl Ehters: Reversible Addition-Fragmentation Chain Transfer Polymerization of Hydroxy Functional Vinyl Ethers", Macromolecules 49, 1563-1574 (2016) 

Shinji Sugihara,* Akmal Hadi Ma'Radzi, Shota Ida, Satoshi Irie, Takamaru Kikukawa, Yasushi Maeda, "In situ nano-objects via RAFT aqueous dispersion polymerization of 2-methoxyethyl acrylate using poly(ethylene oxide) macromolecular chain transfer agemt as steric stabilizer", Polymer, 76, 17-24 (2015) 
   
Shinji Sugihara,* Naoto Konegawa, Yasushi Maeda, "HCl·Et2O-Catalyzed Metal-Free RAFT Cationic Polymerization: One-Pot Transformation from Metal-Free Living Cationic Polymerization to RAFT Radical Polymerization", Macromolecules, 48, 5120-5131 (2015). 

Shinji Sugihara,* In Encyclopedia of Polymeric Nanomaterials, "Petroleum resin", pp.1546-1550, Springer 2015.

Shinji Sugihara,* Akmal Hadi Ma'Radzi, Shota Ida, Satoshi Irie, Takamaru Kikukawa, Yasushi Maeda, "In situ nano-objects via RAFT aqueous dispersion polymerization of 2-methoxyethyl acrylate using poly(ethylene oxide) macromolecular chain transfer agemt as steric stabilizer", Polymer, 76, 17-24 (2015). Shinji Sugihara,* Naoto Konegawa, Yasushi Maeda, "HCl·Et2O-Catalyzed Metal-Free RAFT Cationic Polymerization: One-Pot Transformation from Metal-Free Living Cationic Polymerization to RAFT Radical Polymerization", Macromolecules, 48, 5120-5131 (2015).  

Akmal Hadi Ma'Radzi, Shinji Sugihara,* Takumi Toida, Yasushi Maeda, "Synthesis of polyvinyl alcohol stereoblock copolymer via the combination of living cationic polymerization and RAFT/MADIX polymerization using xanthate with vinyl ether moiety", Polymer, 55, 5332-5345 (2014).

Akmal Hadi Ma'Radzi, Shinji Sugihara,* Soichiro Miura, Naoto Konegawa, Yasushi Maeda, "Synthesis of thermoresponsive block and graft copolymers via the combination of living cationic polymerization and RAFT polymerization using a vinyl ether-type RAFT agent", Polymer, 55, 1920-1930 (2014). 

Shinji Sugihara,* Keiji Iwata, Soichiro Miura, Akmal Hadi Ma'Radzi, Yasushi Maeda, "Synthesis of dual thermoresponsive ABA triblock copolymers by both living cationic vinyl polymerization and RAFT polymerization using a dicarboxylic RAFT agent", Polymer, 54, 1043-1052 (2013).

Tetsuya Hirano, Shinji Sugihara, Yasushi Maeda,* "Infrared Spectriscopic Study on Hydration and Chiral Interaction of Temperature-Responsive Polymer with L-Proline Moieties", J. Phys. Chem. B, 117, 16356-16362 (2013).    

Lee A. Fielding,* Matthew J. Derry, Vincent Ladmiral, Julien Rosselgong, Aurélie M. Rodrigues, Liam P. D. Ratcliffe, Shinji Sugihara, Steven P. Armes,* "RAFT dispersion polymerization in non-polar solvents: facile production of block copolymer spheres, worms and vesicles in n-alkanes", Chem. Sci., 4, 2081-2087 (2013). 

Takashi Hidaka, Shinji Sugihara, Yasushi Maeda,* "Infrared spectriscopic study on LCST behavior of poly(N,N-bis(2-methoxyethyl)acrylamide)", Eur. Polym. J., 49, 675-681 (2013).

Shinji Sugihara,* Kenta Yamashita, Keiji Matsuzuka, Isao Ikeda, Yasushi Maeda, "Transformation of Living Cationic Polymerization of Vinyl Ethers to RAFT Polymerization Mediated by a Carboxylic RAFT Agent", Macromolecules, 45, 794-804 (2012).    

Shinji Sugihara,* "Synthesis of Various Block Copolymers via Precision Polymerizations with Application to Nano-Organizations", KOBUNSHI RONBUNSHU, 69, 567-579 (2012).    

Tao Liu, Jianhong Chen, Shinji Sugihara, Yasushi Maeda*, "Stury on hydration of poly(N-vinylcaprolactam) microgels by near-IR and mid-IR spectroscopy", Colloid Polym. Sci., 290, 763-767 (2012).        

Shinji Sugihara,* Adam Blanazs, Steven P. Armes,* Anthony J. Ryan, Andrew L. Lewis, "Aqueous Dispersion Polymerization: A New Paradigm for in Situ Block Copolymer Self-Assembly in Concentrated Solution", J. Am. Chem. Soc., 133, 15707-15713 (2011).

Shinji Sugihara,* Steven P. Armes,* Adam Blanazs, Andrew L. Lewis, "Non-spherical morphologies from cross-linked biomimetic diblock copolymers using RAFT aqueous dispersion polymerization", Soft Matter, 7, 10787-10793 (2011).        

Shinji Sugihara,"One-Pot Transformation of Living Cationic to RAFT Polymerization", 高分子, 62, 795 (2011).    

Shinji Sugihara,* Kana Sugihara (nee Nishikawa), Steven P. Armes,* Hasan Ahmad, Andrew L. Lewis, "Synthesis of Biomimetic Poly(2-(methacryloyloxy)ethyl phosphorylcholine) Nanolatexes via Atom Transfer Radical Dispersion Polymerization in Alcohol/Water Mixtures", Macromolecules, 43, 6321-6329 (2010).    
Shinji Sugihara,* Sayaka Ito, Satoshi Irie, Isao Ikeda, "Synthesis of Thermoresponsive Shell Cross-Linked Micelles via Living Cationic Polymerization and UV Irradiation", Macromolecules, 43, 1753-1760 (2010).    
Shinji Sugihara,* Steven P. Armes,* Andrew L. Lewis, "One-Pot Synthesis of Biomimetic Shell Cross-Linked Micelles and Nanocages by ATRP in Alcohol/Water Mixtures", Angew. Chem. Int. Ed., 49, 3500-3503 (2010).    
Shinji Sugihara,* Masaru Kitagawa, Yuichi Inagawa, Izabela M. Zaleska, Isao Ikeda, "Effects of monomer and ether structure on metal-free living cationic polymerization of various vinyl ethers using hydrogen chloride with ether", Polym. Bull., 64, 209-220 (2010).    

Izabela M. Zaleska, Masaru Kitagawa, Shinji Sugihara,* Isao Ikeda, "Synthesis of biocompatible and biodegradable block copolymers of polyvinyl alcohol-block-Poly(ε-caprolactone) using metal-free living cationic polymerization", J. Polym. Sci. Part A: Polym. Chem. 47, 5169-5179 (2009).         

Shinji Sugihara,* Yasuaki Tanabe, Masaru Kitagawa, Isao Ikeda, "Facile metal-free living cationic polymerization of various vinyl ethers by harogen chloride with ether", J. Polym. Sci. Part A: Polym. Chem. 46, 1913-1918 (2008).    

Hiroyuki Shimizu, Shinji Sugihara, Isao Ikeda,* "Polymerization of Ctclic Esters in the Presence of Hydroxyl-containing Polymers in DMSO/TBAF", Sen'i Gakkaishi, 64, 57-61 (2008).    

Shinji Sugihara,* Masayuki Ohashi, Isao Ikeda, "Synthesis of Fine Hydrogel Microspheres and Capsules from Thermoresponsive Coacervate", Macromolecules, 40, 3394-3401 (2007).   

Shinji Sugihara,* Akmal Hadi Ma'Radzi, Shinya Hori, Isao Ikeda, "Controlled radical polymerization of methyl methacrylate in the presence of 2-bromoethanol", Polym. Bull., 58, 873-879 (2007).    

Yasushi Maeda,* Hideo Yamauchi, Mie Fujisawa, Shinji Sugihara, Isao Ikeda, Sadahito Aoshima, "Infrared Spectroscopic Invesitigation of Poly(2-methoxyethyl vinyl ether) during Thermosensitive Phase Separation in Water", Langmuir, 23, 6561-6566 (2007). 

Tomoaki Takamoto, Kaori Yasuda, Tomohiro Tsujino, Shinji Sugihara, Shokyoku Kanaoka, Sadahito Aoshima, Yasuhiko Tabata,* "Cell attachment to PET films coated with a thermosensitive block co-polymer with different chemical composition", J. Biomater. Sci. Polym. Ed., 18,1211-1222 (2007).    

Satoshi Okabe, Chieko Fuse, Shinji Sugihara, Sadahito Aoshima, Mitsuhiro Shibayama,* "Structural transition in block and gradient copolymer aqueous solutions", Physica B, 385-386, 356-758 (2006).    

Yasuhiro Matsuda, Takefumi Kawate, Shinji Sugihara, Sadahito Aoshima, Takahiro Sato,* "Structural analysis of aggregates formed by a thermoresponsive homopolymer in dilute aqueous solutions", J. Polym. Sci. Part B: Polym. Phys, 44, 1179-1187 (2006).    

Shinji Sugihara, Shokyoku Kanaoka, Sadahito Aoshima,* "Double Thermosensitive Diblock Copolymers of Vinyl Ethers with Pendant Oxyethylene Groups: Unique Physical Gelation", Macromolecules, 38, 1919-1927 (2005).    

Yasuhiro Matsuda, Yuuji Miyazaki, Shinji Sugihara, Sadahito Aoshima, Kazuya Saito, Takahiro Sato,* "Phase separation behavior of aqueous solutions of a thermoresponsive polymer", J. Polym. Sci. Part B: Polym. Phys, 43, 2937-2949 (2005).    

Shinji Sugihara, Shokyoku Kanaoka, Sadahito Aoshima,* "Stimuli-responsive ABC triblock copolymers by sequential living cationic copolymerization: multistage self-assemblies micellization to open association", J. Polym. Sci. Part A: Polym. Chem., 42, 2601-2611 (2004).

Shinji Sugihara, Shokyoku Kanaoka, Sadahito Aoshima,* "Thermosensitive Random Copolymers of Hydrophilic and Hydrophobic Monomers Obtained by Living Cationic Copolymerization", Macromolecules, 37, 1711-1719 (2004).    

Shinji Sugihara, Kiyotaka Hashimoto, Satoshi Okabe, Mitsuhiro Shibayama, Sadahito Aoshima,* "Stimuli-Responsive Diblock Copolymers by Living Cationic Polymerization: Precision Synthesis and Highly Sensitive Physical Gelation", Macromolecules, 37, 336-343 (2004).    

Chieko Fuse, Satoshi Okabe, Shinji Sugihara, Sadahito Aoshima, Mitsuhiro Shibayama,* "Water-Induced Self-Assembling of Solvent-Sensitive Block Copolymer", Macromolecules, 37,7791-7798 (2004).    

Sadahito Aoshima,* Shinji Sugihara, Mitsuhiro Shibayama, Shokyoku Kanaoka, "Synthesis and Self-Association of Stimuli-Responsive Diblock Copolymers by Living Cationic Polymerization", Macromol. Symp., 215, 151-163 (2004).

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