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Graduate School of Engineering, Department of Applied Chemistry & Biotechnology Japanese

representative Publications (2004-Present)

2025年

Shinji Sugihara, Atsushi Endo, Komal Raje, Atsushi Matsumoto, Satoshi Fujita, Yasushi Maeda,"Design and Synthesis of Thermoresponsive Degradable Copolymers: Integrating Hydroxy-Functional Vinyl Ethers with Cyclic Ketene Acetals",
Polym. Chem.,
16, 3059-3069 (2025)


Hideyuki Uematsu, Shunya Yorikane, Ayaka Yamaguchi, Shinji Sugihara, Fumihiro Nishimura. Masachika Yamane, Shuichi Tanoue,"Role of glass fiber surface treatment on hydrothermal aging at the interface between polybutylene terephthalate and glass fiber",
Compos. Part A: Appl. Sci. Manuf.,
192, 108811 (2025)


Atsushi Matsumoto, Maria Ikeda, Shinji Sugihara, Yasushi Maeda,"Viscometric Method for Estimating the Charge Fraction of Polyelectrolytes in Solutions",
J. Soc. Rheol., Jpn.,
53, 1-10 (2025)
 

Hideyuki Uematsu,Toumu Aratama, Ken Sudo, Yukino Ito, Ayaka Yamaguchi, Akinori Fukushima, Shinji Sugihara, Fumihiro Nishimura, Masachika Yamane, Shuichi Tanoue,"Antioxidant-enhanced interfacial adhesion and mechanical properties of polyetheretherketone–carbon fiber composites",
Polymer,
328, 128415 (2025)


Hideyuki Uematsu, Shunya Yorikanea, Ayaka Yamaguchi, Shinji Sugihara, Fumihiro Nishimura, Masachika Yamane, Shuichi Tanouea,"Surface design of glass fiber for polyphenylene sulfide and spectroscopic characterization of structures at interface/interphase",
Compos. B Eng.,
Aug, 112868 (2025)

2024年

Shinji Sugihara, Yuto Tsutsui, Hideyuki Uematsu, Atsushi Matsumoto, Yasushi Maeda, "Synthesis of Flower-like Micelles That Recognize Thermal History via RAFT Aqueous Dispersion Polymerization",
Macromolecules,
57, 4524-4535 (2024)
 
Mugen Yamawaki, Kota Matsumoto, Toshiki Furutani, Shinji Sugihara, Yasuharu Yoshimi, "Visible-light-induced Decarboxylative Polymerization in Two-Molecule Photoredox System",
Polymer,
308, 127336 (2024)
 
Hideyuki Uematsu, Miyuki Doi, Shunya Yorikane, Ayaka Yamaguchi, Fumihiro Nishimura, Shinji Sugihara, Masachika Yamane, Yukihiro Ozaki, Shuichi Tanoue, "Influence of Polyetheretherketone radicals on interfacial interaction with carbon fiber and crystal formation of Polyetheretherketone at the interphase",
Surfaces and Interfaces,
49, 104409 (2024)
 
Book 1 pp.400-410, NTS (2024)

Book 2 Dispersion

2023年

Hideyuki Uematsu*, Shunya Nishimura, Ayaka Yamaguchi, Fumihiro Nishimura, Shinji Sugihara, Naoki Sugiura, Takeshi Ishikawa, Takahiro Hayashi, Masachika Yamane, Kazumasa Kawabe, Yukihiro Ozaki, Shuichi Tanoue, "Crystal structures of polyamide 6 at the interphase and around carbon fiber and mechanical properties of their composites",
Polymer,
275, 125907 (2023)
 
Hideyuki Uematsu, Miyuki Doi, Shunya Yorikane, Ayaka Yamaguchi, Fumihiro Nishimura, Shinji Sugihara, Masachika Yamane, Yukihiro Ozaki, Shuichi Tanoue, "Enhancement of Interfacial Adhesion to Carbon Fibers via Electrostatic Interaction Using Polyvinyl chloride as a Model Matrix",
Surfaces and Interfaces,
42, 103287 (2023)
 
Hideyuki Uematsu, Kotaro Mune, Ayaka Yamaguchi, Shinji Sugihara, Shotaro Nishitsuji, Fumihiro Nishimura, Masachika Yamane, Yukihiro Ozaki, Shuichi Tanoue "Promotion of crystallization of polyamide 6 at an interphase and a mechanical interlocking effect at an interface due to surface irregularities of carbon fibers",
Polymer
284, 126290 (2023)
 
Hideyuki Uematsu, Maya Ishikawa, Ayaka Yamaguchi, Shinji Sugihara, Shotaro Nishitsuji, Fumihiro Nishimura, Masachika Yamane, Kazumasa Kawabe, Yukihiro Ozaki, Shuichi Tanoue "Enhancement of Flexural Properties of Carbon Fiber-Reinforced Polyamide 6 via Oriented Crystallization of Polyamide 6 among Carbon Fibers",
Composites Part A: Applied Science and Manufacturing,
176, 107837 (2023)
Hideyuk Uematsu, Kou Yoshida, Ayaka Yamaguchi, Akinori Fukushima, Shinji Sugihara, Masachika Yamane, Yukihiro Ozaki, Shuichi Tanoue, "Enhancement of interfacial shear strength due to cooperative π-π interaction between polyphenylene sulfide and carbon fiber and molecular orientation of polyphenylene sulfide via the π-π interaction"Composites Part A: Applied Science and Manufacturing, 165, 107355 (2023)  

2022年

Shinji Sugihara,* "From controlled radical polymerization of vinyl ether to polymerization-induced self-assembly",
Polym. J.
54, 1407-1481 (2022)
  
Hideyuki Uematsu, Naoki Higashitani, Ayaka Yamaguchi, Akinori Fukuishima, Takayuki Asano, Seitaro Mitsudo, Shinji Sugihara, Masachika Yamane, Toshihira Irisawa,Yukihiro Ozaki, ShuichiTanoue, "Effects of polycarbonate crystals, π-π interactions, and chemical bonds at an interface on the interfacial adhesion between polycarbonate and reinforcing fibers",
Surf. Interfaces, 34, 102300 (2022)  
Atsushi Matsumoto, Ryosuke Ukai, Hiroto Osada, Shinji Sugihara, and Yasushi Maeda, "Tuning the Solution Viscosity of Ionic-Liquid-Based Polyelectrolytes with Solvent Dielectric Constants via the Counterion Condensation",
Macromolecules, 55, 10600-10606 (2022)  
Atsushi Takashima, Yasushi Maeda, Shinji Sugihara, "Morphology Control via RAFT Emulsion Polymerization-Induced Self-Assembly: Systematic Investigation of Core-Forming Blocks",
ACS Omega, 7, 26894-26904 (2022)  
Yuka Sumikama, Atushi Takashima, Tomohiro Mochizuki, Haruhiko Sakuraba, Toshihisa Ohshima, Shinji Sugihara, Shin-ichiro Suye, Takenori Satomura "Self-assembly of Aeropyrum pernix bacilliform virus 1 (APBV1) major capsid protein and its application as building blocks for nanomaterials",
Extremophile, 26, 34 (2022)  
Hideyuki Uematsu, Kotaro Mune, Shunya Nishimura, Koutarou Koizumi, Ayaka Yamaguchi, Shinji Sugihara, Masachika Yamane, Kazumasa Kawabe, Yukihiro Ozaki, Shuichi Tanoue, "Fracture properties of quasi-isotropic carbon-fiber-reinforced polyamide 6 laminates with different crystal structure of polyamide 6 due to surface profiles of carbon fibers",
Compos. Part A Appl. Sci. Manuf.,
154, 106752 (2022)
 
Narumi Asano, Shinji Sugihara, Shin-ichiro Suye, and Satoshi Fujita, Electrospun Porous Nanofibers with Imprinted Patterns Induced by Phase Separation of Immiscible Polymer Blends",
ACS Omega, 7, 19997-20005 (2022)  

Hideyuki Uematsu,Takahiro Kawasaki, Koutaro Koizumi, Akane Yamaguchi, Shinji Sugihara, Masachika Yamane, Kazumasa Kawabe, Yukihiro Ozaki, Shuichi Tanoue, "Relationship between crystalline structure of polyamide 6 within carbon fibers and their mechanical propaerties studied using Micro-Raman spectroscopy", Polymer, 223, 123711 (2021)  

Shinji Sugihara, Ryuya Kawakami, Satoshi Irie, Yasushi Maeda, "Poly[di(ethylene glycol) vinyl ether]-stabilized poly(vinyl acetate) nanoparticles with various morphologies via RAFT aqueous emulsion polymerization of vinyl acetate", Polym. J., 53, 309-321 (2021)  

Satoshi Fujita, Saeri Hara, Akari Hosono, Shinji Sugihara, Hideyuki Uematsu, Shin-ichiro Suye, "Hyaluronic Acid Hydrogel Crosslinked with Complementary DNAs", Adv. Polym. Technol.,2020, 1470819 (2020)

Shinji Sugihara,* Ayano Yoshida, Taka-aki Kono, Tsuyoshi Takayama, Yasushi Maeda, "Controlled Radical Homopolymerization of Representative Cationically Polymerizable Vinyl Ethers", J. Am. Chem. Soc.,141, 13954-13961 (2019)

Shinji Sugihara,* Molecular Technology, Volume 4: Synthesis Innovation(H. Yamamoto, T.Kato ed.) Chapter 1. "Polymerization-Induced Self-assembly of Block Copolymer Nano-objects via Green RAFT Polymerization")
     
Shinji Sugihara,* Masahiro Sudo, Yasushi Maeda, "Synthesis and Nano-object Assembly of Biomimetic Block Copolymers for Catalytic Silver Nanoparticles", Langmuir 35, 1346-1356 (2019)     

Shinji Sugihara,* Yoshihiro Sakamoto, Masakazu Nakayama, Keigo Michishita, Yasushi Maeda,"Transformation from xanthate-type cationogen mediated metal-free RAFT cationic polymerization with “HCl·Et2O” into RAFT radical polymerization to form poly(alkyl vinyl ether)-b-polyvinyl alcohol amphiphiles", Polymer 154, 153-163 (2018)

Shinji Sugihara,* Masahiro Sudo, Kazumasa Hirogaki, Satoshi Irie, Yasushi Maeda, "Synthesis of Various Poly(2-hydroxyethyl vinyl ethe)-Stabilized Latex Particles via Surfactant-Free Emulsion Polymerization in Water", Macromolecules 51, 1260-1271 (2018)

Shinji Sugihara,* Ayano Yoshiada, Satoshi Fujita, Yasushi Maeda, "Design of Hydroxy- Functionalized Thermoresponsive Copolymers: Improved Direct Radical Polymerization of Hydroxy-Functional Vinyl Ethers", Macromolecules 50, 8346-8356 (2017)

Mugen Yamawaki, Akari Ukai, Yuki Kamiya, Shinji Sugihara,* Miku Sakai, Yasuharu Yoshimi,* "Metal-Free Photoinduced Decarboxylative Radical Polymerization Using Carboxylic Acids as Benign Radical Initiators: Introduction of Complex Molecules into Polymer Chain Ends", ACS Macro Letters, 6, 381-385(2017)

Shinji Sugihara,* Seiya Okubo, Yasushi Maeda, "Metal-free RAFT cationic polymerization of p-methoxystyrene with HCl・Et2O using a xanthate-type RAFT cationogen", Polymer Chemistry 7, 6854-6863 (2016)

Shinji Sugihara,* Yuki Kawamoto, Yasushi Maeda, "Direct Radical Polymerization of Vinyl Ehters: Reversible Addition-Fragmentation Chain Transfer Polymerization of Hydroxy Functional Vinyl Ethers", Macromolecules 49, 1563-1574 (2016) 

Shinji Sugihara,* Akmal Hadi Ma'Radzi, Shota Ida, Satoshi Irie, Takamaru Kikukawa, Yasushi Maeda, "In situ nano-objects via RAFT aqueous dispersion polymerization of 2-methoxyethyl acrylate using poly(ethylene oxide) macromolecular chain transfer agemt as steric stabilizer", Polymer, 76, 17-24 (2015) 
   
Shinji Sugihara,* Naoto Konegawa, Yasushi Maeda, "HCl·Et2O-Catalyzed Metal-Free RAFT Cationic Polymerization: One-Pot Transformation from Metal-Free Living Cationic Polymerization to RAFT Radical Polymerization", Macromolecules, 48, 5120-5131 (2015). 

Shinji Sugihara,* In Encyclopedia of Polymeric Nanomaterials, "Petroleum resin", pp.1546-1550, Springer 2015.

Shinji Sugihara,* Akmal Hadi Ma'Radzi, Shota Ida, Satoshi Irie, Takamaru Kikukawa, Yasushi Maeda, "In situ nano-objects via RAFT aqueous dispersion polymerization of 2-methoxyethyl acrylate using poly(ethylene oxide) macromolecular chain transfer agemt as steric stabilizer", Polymer, 76, 17-24 (2015). Shinji Sugihara,* Naoto Konegawa, Yasushi Maeda, "HCl·Et2O-Catalyzed Metal-Free RAFT Cationic Polymerization: One-Pot Transformation from Metal-Free Living Cationic Polymerization to RAFT Radical Polymerization", Macromolecules, 48, 5120-5131 (2015).  

Akmal Hadi Ma'Radzi, Shinji Sugihara,* Takumi Toida, Yasushi Maeda, "Synthesis of polyvinyl alcohol stereoblock copolymer via the combination of living cationic polymerization and RAFT/MADIX polymerization using xanthate with vinyl ether moiety", Polymer, 55, 5332-5345 (2014).

Akmal Hadi Ma'Radzi, Shinji Sugihara,* Soichiro Miura, Naoto Konegawa, Yasushi Maeda, "Synthesis of thermoresponsive block and graft copolymers via the combination of living cationic polymerization and RAFT polymerization using a vinyl ether-type RAFT agent", Polymer, 55, 1920-1930 (2014). 

Shinji Sugihara,* Keiji Iwata, Soichiro Miura, Akmal Hadi Ma'Radzi, Yasushi Maeda, "Synthesis of dual thermoresponsive ABA triblock copolymers by both living cationic vinyl polymerization and RAFT polymerization using a dicarboxylic RAFT agent", Polymer, 54, 1043-1052 (2013).

Tetsuya Hirano, Shinji Sugihara, Yasushi Maeda,* "Infrared Spectriscopic Study on Hydration and Chiral Interaction of Temperature-Responsive Polymer with L-Proline Moieties", J. Phys. Chem. B, 117, 16356-16362 (2013).    

Lee A. Fielding,* Matthew J. Derry, Vincent Ladmiral, Julien Rosselgong, Aurélie M. Rodrigues, Liam P. D. Ratcliffe, Shinji Sugihara, Steven P. Armes,* "RAFT dispersion polymerization in non-polar solvents: facile production of block copolymer spheres, worms and vesicles in n-alkanes", Chem. Sci., 4, 2081-2087 (2013). 

Takashi Hidaka, Shinji Sugihara, Yasushi Maeda,* "Infrared spectriscopic study on LCST behavior of poly(N,N-bis(2-methoxyethyl)acrylamide)", Eur. Polym. J., 49, 675-681 (2013).

Shinji Sugihara,* Kenta Yamashita, Keiji Matsuzuka, Isao Ikeda, Yasushi Maeda, "Transformation of Living Cationic Polymerization of Vinyl Ethers to RAFT Polymerization Mediated by a Carboxylic RAFT Agent", Macromolecules, 45, 794-804 (2012).    

Shinji Sugihara,* "Synthesis of Various Block Copolymers via Precision Polymerizations with Application to Nano-Organizations", KOBUNSHI RONBUNSHU, 69, 567-579 (2012).    

Tao Liu, Jianhong Chen, Shinji Sugihara, Yasushi Maeda*, "Stury on hydration of poly(N-vinylcaprolactam) microgels by near-IR and mid-IR spectroscopy", Colloid Polym. Sci., 290, 763-767 (2012).        

Shinji Sugihara,* Adam Blanazs, Steven P. Armes,* Anthony J. Ryan, Andrew L. Lewis, "Aqueous Dispersion Polymerization: A New Paradigm for in Situ Block Copolymer Self-Assembly in Concentrated Solution", J. Am. Chem. Soc., 133, 15707-15713 (2011).

Shinji Sugihara,* Steven P. Armes,* Adam Blanazs, Andrew L. Lewis, "Non-spherical morphologies from cross-linked biomimetic diblock copolymers using RAFT aqueous dispersion polymerization", Soft Matter, 7, 10787-10793 (2011).        

Shinji Sugihara,"One-Pot Transformation of Living Cationic to RAFT Polymerization", 高分子, 62, 795 (2011).    

Shinji Sugihara,* Kana Sugihara (nee Nishikawa), Steven P. Armes,* Hasan Ahmad, Andrew L. Lewis, "Synthesis of Biomimetic Poly(2-(methacryloyloxy)ethyl phosphorylcholine) Nanolatexes via Atom Transfer Radical Dispersion Polymerization in Alcohol/Water Mixtures", Macromolecules, 43, 6321-6329 (2010).    
Shinji Sugihara,* Sayaka Ito, Satoshi Irie, Isao Ikeda, "Synthesis of Thermoresponsive Shell Cross-Linked Micelles via Living Cationic Polymerization and UV Irradiation", Macromolecules, 43, 1753-1760 (2010).    
Shinji Sugihara,* Steven P. Armes,* Andrew L. Lewis, "One-Pot Synthesis of Biomimetic Shell Cross-Linked Micelles and Nanocages by ATRP in Alcohol/Water Mixtures", Angew. Chem. Int. Ed., 49, 3500-3503 (2010).    
Shinji Sugihara,* Masaru Kitagawa, Yuichi Inagawa, Izabela M. Zaleska, Isao Ikeda, "Effects of monomer and ether structure on metal-free living cationic polymerization of various vinyl ethers using hydrogen chloride with ether", Polym. Bull., 64, 209-220 (2010).    

Izabela M. Zaleska, Masaru Kitagawa, Shinji Sugihara,* Isao Ikeda, "Synthesis of biocompatible and biodegradable block copolymers of polyvinyl alcohol-block-Poly(ε-caprolactone) using metal-free living cationic polymerization", J. Polym. Sci. Part A: Polym. Chem. 47, 5169-5179 (2009).         

Shinji Sugihara,* Yasuaki Tanabe, Masaru Kitagawa, Isao Ikeda, "Facile metal-free living cationic polymerization of various vinyl ethers by harogen chloride with ether", J. Polym. Sci. Part A: Polym. Chem. 46, 1913-1918 (2008).    

Hiroyuki Shimizu, Shinji Sugihara, Isao Ikeda,* "Polymerization of Ctclic Esters in the Presence of Hydroxyl-containing Polymers in DMSO/TBAF", Sen'i Gakkaishi, 64, 57-61 (2008).    

Shinji Sugihara,* Masayuki Ohashi, Isao Ikeda, "Synthesis of Fine Hydrogel Microspheres and Capsules from Thermoresponsive Coacervate", Macromolecules, 40, 3394-3401 (2007).   

Shinji Sugihara,* Akmal Hadi Ma'Radzi, Shinya Hori, Isao Ikeda, "Controlled radical polymerization of methyl methacrylate in the presence of 2-bromoethanol", Polym. Bull., 58, 873-879 (2007).    

Yasushi Maeda,* Hideo Yamauchi, Mie Fujisawa, Shinji Sugihara, Isao Ikeda, Sadahito Aoshima, "Infrared Spectroscopic Invesitigation of Poly(2-methoxyethyl vinyl ether) during Thermosensitive Phase Separation in Water", Langmuir, 23, 6561-6566 (2007). 

Tomoaki Takamoto, Kaori Yasuda, Tomohiro Tsujino, Shinji Sugihara, Shokyoku Kanaoka, Sadahito Aoshima, Yasuhiko Tabata,* "Cell attachment to PET films coated with a thermosensitive block co-polymer with different chemical composition", J. Biomater. Sci. Polym. Ed., 18,1211-1222 (2007).    

Satoshi Okabe, Chieko Fuse, Shinji Sugihara, Sadahito Aoshima, Mitsuhiro Shibayama,* "Structural transition in block and gradient copolymer aqueous solutions", Physica B, 385-386, 356-758 (2006).    

Yasuhiro Matsuda, Takefumi Kawate, Shinji Sugihara, Sadahito Aoshima, Takahiro Sato,* "Structural analysis of aggregates formed by a thermoresponsive homopolymer in dilute aqueous solutions", J. Polym. Sci. Part B: Polym. Phys, 44, 1179-1187 (2006).    

Shinji Sugihara, Shokyoku Kanaoka, Sadahito Aoshima,* "Double Thermosensitive Diblock Copolymers of Vinyl Ethers with Pendant Oxyethylene Groups: Unique Physical Gelation", Macromolecules, 38, 1919-1927 (2005).    

Yasuhiro Matsuda, Yuuji Miyazaki, Shinji Sugihara, Sadahito Aoshima, Kazuya Saito, Takahiro Sato,* "Phase separation behavior of aqueous solutions of a thermoresponsive polymer", J. Polym. Sci. Part B: Polym. Phys, 43, 2937-2949 (2005).    

Shinji Sugihara, Shokyoku Kanaoka, Sadahito Aoshima,* "Stimuli-responsive ABC triblock copolymers by sequential living cationic copolymerization: multistage self-assemblies micellization to open association", J. Polym. Sci. Part A: Polym. Chem., 42, 2601-2611 (2004).

Shinji Sugihara, Shokyoku Kanaoka, Sadahito Aoshima,* "Thermosensitive Random Copolymers of Hydrophilic and Hydrophobic Monomers Obtained by Living Cationic Copolymerization", Macromolecules, 37, 1711-1719 (2004).    

Shinji Sugihara, Kiyotaka Hashimoto, Satoshi Okabe, Mitsuhiro Shibayama, Sadahito Aoshima,* "Stimuli-Responsive Diblock Copolymers by Living Cationic Polymerization: Precision Synthesis and Highly Sensitive Physical Gelation", Macromolecules, 37, 336-343 (2004).    

Chieko Fuse, Satoshi Okabe, Shinji Sugihara, Sadahito Aoshima, Mitsuhiro Shibayama,* "Water-Induced Self-Assembling of Solvent-Sensitive Block Copolymer", Macromolecules, 37,7791-7798 (2004).    

Sadahito Aoshima,* Shinji Sugihara, Mitsuhiro Shibayama, Shokyoku Kanaoka, "Synthesis and Self-Association of Stimuli-Responsive Diblock Copolymers by Living Cationic Polymerization", Macromol. Symp., 215, 151-163 (2004).

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